A new binuclear MoV–DyIII assembly and its magnetism
Shi Rena, b, Shu-Lin Maa, Gong-Feng Xua, Bin Gub, Yue Mab, 
, 
, Qing-Lun Wangb and Dai-Zheng Liaob, ,
Received 3 November 2010;
accepted 8 April 2011.
Available online 16 April 2011.
Abstract
The reaction of [Mo(CN)8]3− with Dy3+ in DMF solvent leads to a new binuclear complex, [Mo(CN)8Dy(DMF)4(H2O)3]·H2O (1) (DMF = N,N′-dimethylformamide). Magnetic measurements confirm that 1 presents probably a ferromagnetic interaction between the binuclear complexes.
Graphical abstract
Construct a binuclear MoV–DyIII complex, in which the coordination sphere of Dy and Mo atoms lie in a slightly distorted trigonal dodecahedron geometry and linked by cyanide group.
