30.08.2007
Austrian NANO Initiative
„National cooperative Research and Technological Development in Cluster projects”
PHONAS
Photocatalytic
Nano Layers
Objectives
Development of new transparent self-cleaning and –sterilizing coatings based on
photocatalytic nano-particles (PCNP).
development of PCNP with selective surface functionalisation
development of PCNP with increased photocatalytic activity in the visible light region
development of processes and equipment for continues production of PCNP and
coatings
Application of new PCNP and coating processes
Project description
The RPC PHONAS integrates 4
complementary Research Projects (RP) with
a high mutual interdependence. The overall
goal is to develop the scientific and
technological basis for new transparent selfcleaning
and –sterilizing coatings based on
photocatalytic nano-particles (PCNP).
PHONAS combines high level expertise in
chemistry, physics, material science,
processing, mechanical engineering and
characterisation on the RTD side, with
industrial competences in the fields of
laminated furniture panels, sanitary
installations, stones, cleaning & coating and
machinery. PHONAS seeks to build up within
4 years a genuine Austrian competence for self-cleaning and –sterilizing PCNP-coatings,
both in scientific, and technological terms. The economic relevance stems from the
generation of new, competitive and value-adding coatings that can be deposited on different
materials including polymers, for the purpose of self-cleaning and -sterilisation. By adding
value to otherwise inactive surfaces, coated products will have the potential to gain
exceptional profits.
The PHONAS consortium is made up of 4 RTD partners and 9 participants from industry with
a significant number of SMEs. Within the 4 complementary Research Projects the scientific
objectives are pursued in the RP’s JANPAR and BANPA:
JANPAR is focussed on the development of new PCNPs based on TiO2 with selective
surface functionalisation (“Janus particles”), so that the photocatalytic action can be
oriented in a way not to attack the substrate and/or the matrix containing organic
constituents. These new particle should also have the ability for self-assembling. The
outcome will be transferred to the applied RPs as input for the technology
development.
In BANPA advanced wet chemistry will be used to develop novel PCNPs on the basis
of TiO 2 or WO3 that permit the utilization of visible light, so that the photocatalytic
effect can be employed for indoor applications. Tuning the absorption band gap will
be accomplished by control of the particle size and by the design of composite
particles. This work will be carried out in close co-operation with JANPAR. The results
will be conveyed to the applied RPs.
Built upon the contributions from the scientific RPs the technological objectives are pursued
in the applied RPs TESET and TEPCO:
The superhydrophilic photocatalytic effect, shown
on a coated glass. The left side is uncoated and
shows the typical water droplets. The right side is
coated with a photocatalytic active material and
therefore keeps transparent.
2
TESET will develop a machine, which permits the continuous production of high
quality PCNPs by a wet chemistry precipitation process, which is suited for up-scaling
to an industrial level. It will be combined with a coating unit to form a “tandem-device”
on pilot scale level. It will be optimized to process the new PCNPs originating from
the scientific RPs.
In TEPCO the developments of the other RPs will be utilized to develop new pilot
scale PCNP-coatings with superior self-cleaning or –sterilizing properties, while
maintaining secondary properties like hardness or wear resistance. Selected model
substrates from industry based on polymers, metals and glass will be coated, tested
and optimized for subsequent up-scaling and exploitation. As an alternative for
metals, PCNPs will be embedded in a metallic matrix by a galvanic process
(dispersion coatings).
Number of RTD projects in the cluster: 4 RTD projects
Recent funding period: 2 years
Overall planned duration: 4 years
Project volume: Total costs which have been accepted so far: EUR 2.589.719 ,-
Funding: EUR 1.617.709 ,- (62,5% of accepted elegible costs)
Project partners
Scientific partners: Austrian Research Centers GmbH – ARC; Vienna University of Technology,
Institute of Materials Chemistry; University of Advanced Study Wiener Neustadt for Economy and
Technology GmbH; ECHEM Center of Competence in Applied Electrochemistry
Industrial partners: FunderMax GmbH; Längle Pulverbeschichtung GmbH; Fabachem astleithner
GmbH; Artweger GmbH & Co; Rupert Fertinger GmbH; Poschacher Natursteinwerke GmbH & Co KG;
Engineered nanoProducts Germany GmbH (Austria); Hochdruckprodukte Maschinen- und
Apparatebau Gesellschaft m.b.H. (HDP); Profactor Research and Solutions GmbH
Associated partner: Institut für Neue Materialien GmbH
Project coordinator: Dr. Nils Stelzer, MSc.; Functional Materials; Austrian Research Centers
GmbH-ARC; 2444 Seibersdorf; Tel.: +43-664-8251293; +43(0)505503351; Fax.: +43-(0)50550-3366;
E-mail: nils.stelzer@arcs.ac.at; www.arcs.ac.at; www.phonas.at
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