12.09.2009
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 12.09.2009   Карта сайта     Language По-русски По-английски
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12.09.2009

Nature 461, 246-249 (10 September 2009) | doi:10.1038/nature08288; Received 16 February 2009; Accepted 13 July 2009



Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts


Minkee Choi1,7, Kyungsu Na1,7, Jeongnam Kim1,2, Yasuhiro Sakamoto5,6, Osamu Terasaki4,6 & Ryong Ryoo1,2,3




  1. Center for Functional Nanomaterials, Department of Chemistry, KAIST,

  2. Graduate School of Nanoscience and Technology (WCU), KAIST,

  3. KAIST Institute for the NanoCentury,

  4. Graduate School of EEWS (WCU), KAIST, Daejeon 305-701, Korea

  5. Structural Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm, Sweden

  6. Nanoscience and Nanotechnology Research Center, Osaka Prefecture University, Sakai 599-8570, Japan

  7. These authors contributed equally to this work.


Correspondence to: Ryong Ryoo1,2,3 Correspondence and requests for materials should be addressed to R.R. (Email: rryoo@kaist.ac.kr).





Zeolites—microporous crystalline aluminosilicates—are widely used in petrochemistry and fine-chemical synthesis1, 2, 3 because strong acid sites within their uniform micropores enable size- and shape-selective catalysis. But the very presence of the micropores, with aperture diameters below 1 nm, often goes hand-in-hand with diffusion limitations3, 4, 5 that adversely affect catalytic activity. The problem can be overcome by reducing the thickness of the zeolite crystals, which reduces diffusion path lengths and thus improves molecular diffusion4, 5. This has been realized by synthesizing zeolite nanocrystals6, by exfoliating layered zeolites7, 8, 9, and by introducing mesopores in the microporous material through templating strategies10, 11, 12, 13, 14, 15, 16, 17 or demetallation processes18, 19, 20, 21, 22. But except for the exfoliation, none of these strategies has produced 'ultrathin' zeolites with thicknesses below 5 nm. Here we show that appropriately designed bifunctional surfactants can direct the formation of zeolite structures on the mesoporous and microporous length scales simultaneously and thus yield MFI (ZSM-5, one of the most important catalysts in the petrochemical industry) zeolite nanosheets that are only 2 nm thick, which corresponds to the b-axis dimension of a single MFI unit cell. The large number of acid sites on the external surface of these zeolites renders them highly active for the catalytic conversion of large organic molecules, and the reduced crystal thickness facilitates diffusion and thereby dramatically suppresses catalyst deactivation through coke deposition during methanol-to-gasoline conversion. We expect that our synthesis approach could be applied to other zeolites to improve their performance in a range of important catalytic applications.



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  • Chen Wev   honorary member of ISSC science council

  • Harton Vladislav Vadim  honorary member of ISSC science council

  • Lichtenstain Alexandr Iosif  honorary member of ISSC science council

  • Novikov Dimirtii Leonid  honorary member of ISSC science council

  • Yakushev Mikhail Vasilii  honorary member of ISSC science council

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